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The first transannular [4+3] cycloaddition reaction: synthesis of the ABCD ring structure of cortistatins
A 14-membered macrocycle with an allene and a furan strategically located at across the ring from each other is synthesized using an allene ring closing metathesis reaction. Upon treatment of the macrocycle with a catalytic amount of Pd(OAc)(2) and other additives, the first transannular [4+3] cyclo...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2008
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597840/ https://ncbi.nlm.nih.gov/pubmed/19812680 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.07.155 |
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