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Metalated Nitriles: Stereodivergent Cation-Controlled Cyclizations1
Stereodivergent cyclizations of γ-hydroxy cyclohexanecarbonitriles are controlled simply through judicious choice of cation in the alkylmetal base. Deprotonating a series of cyclic γ-hydroxy nitriles with i-PrMgBr generates C-magnesiated nitriles that cyclize under stereoelectronic control to cis-fu...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597827/ https://ncbi.nlm.nih.gov/pubmed/19657380 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.05.110 |
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