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Observing In-phase Single-Quantum (15)N Multiplets for NH(2)/NH(3)(+) Groups with Two-dimensional Heteronuclear Correlation Spectroscopy

Two-dimensional (2D) F1-(1)H-coupled HSQC experiments provide 3:1:1:3 and 1:0:1 multiplets for AX(3) and AX(2) spin systems, respectively. These multiplets occur because, in addition to the 2S(+)H(z)(a) → 2S(+)H(z)(a) process, the coherence transfers such as 2S(+)H(z)(a) → 2S(+)H(z)(b) occurring in...

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Detalhes bibliográficos
Main Authors: Takayama, Yuki, Sahu, Debashish, Iwahara, Junji
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2597751/
https://ncbi.nlm.nih.gov/pubmed/18691921
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jmr.2008.07.018
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