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B-Allenyl- and B-(Y-Trimethylsilylpropargyl)-10-phenyl-9-borabicyclo[3.3.2]-decanes: Asymmetric Synthesis of Propargyl and α-Allenyl 3°-Carbinols from Ketones
[Image: see text] Simple and efficient Grignard procedures are reported for the syntheses of B-allenyl-10-(phenyl)-9-borabicyclo[3.3.2]decane (1) and its B-(Y-trimethylsilylpropargyl)- counterpart (2) in both enantiomeric forms. Both add selectively to ketones providing propargyl- and α-silylallenyl...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597672/ https://ncbi.nlm.nih.gov/pubmed/16928081 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061596j |
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