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Origin of Thermodynamic versus Kinetic Control of Allene Hydroboration with 9-Borabicyclo[3.3.1]nonane and 10-R-9-Borabicyclo[3.3.2]decane

[Image: see text] Density functional theory was used to locate transition states for hydroboration reactions of allenes with 9-borabicyclo[3.3.1]nonane and 10-R-9-borabicyclo[3.3.2]decane, as well as transition states for [1,3]-boratropic shift and aldehyde addition reactions of the derived allylbor...

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Detalhes bibliográficos
Main Authors: Ess, Daniel H., Kister, Jeremy, Chen, Ming, Roush, William R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2803353/
https://ncbi.nlm.nih.gov/pubmed/19899749
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol902364d
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