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Antineoplastic Agents 561. Total Synthesis of Respirantin1a

Total synthesis of the eighteen-membered ring cyclodepsipeptide believed to be respirantin (1b) has been achieved. The key step in the synthesis is an intramolecular transesterification of the β-ketoester alcohol 6 to afford the protected macrocycle 5. The synthetic product was shown to be identical...

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Autores principales: Pettit, George R., Smith, Thomas H., Feng, Song, Knight, John C., Tan, Rui, Pettit, Robin K., Hinrichs, Peter A.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2007
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2597657/
https://ncbi.nlm.nih.gov/pubmed/17608531
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/np0680735
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