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Antineoplastic Agents 561. Total Synthesis of Respirantin1a
Total synthesis of the eighteen-membered ring cyclodepsipeptide believed to be respirantin (1b) has been achieved. The key step in the synthesis is an intramolecular transesterification of the β-ketoester alcohol 6 to afford the protected macrocycle 5. The synthetic product was shown to be identical...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2597657/ https://ncbi.nlm.nih.gov/pubmed/17608531 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/np0680735 |
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