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Radical cascades using enantioenriched 7-azabenzonorbornenes and their applications in synthesis
Tandem deoxygenation–neophyl-type radical rearrangement–electrophile trapping using xanthates from 7-azabenzonorbornadienes gives 3-exo-substituted 2-aza-5,6-benzonorbornenes, which in some cases undergo isomerisation to (aminomethyl)indenes. The starting xanthates are accessible in good yields and...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Beilstein-Institut
2008
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587947/ https://ncbi.nlm.nih.gov/pubmed/19043626 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.4.38 |
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