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Orthogonal Pd- and Cu-Based Catalyst Systems for the C- and N-Arylation of Oxindoles
In the cross-coupling reactions of unprotected oxindoles with aryl halides, Pd- and Cu-based catalyst systems displayed orthogonal chemoselectivity. A Pd/dialkylbiarylphosphine-based catalyst system chemoselectively arylated oxindole at the 3-position, while arylation occurred exclusively at the nit...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2008
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587375/ https://ncbi.nlm.nih.gov/pubmed/18588302 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja803179s |
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