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An Inner-Sphere Mechanism for Molecular Oxygen Reduction Catalyzed by Copper Amine Oxidases
Copper and topaquinone (TPQ) containing amine oxidases utilize O(2) for the metabolism of biogenic amines while concomitantly generating H(2)O(2) for use by the cell. The mechanism of O(2) reduction has been the subject of long-standing debate due to the obscuring influence of a proton-coupled elect...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2574554/ https://ncbi.nlm.nih.gov/pubmed/18582059 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja801378f |
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