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Diastereoselective Synthesis of a Simplified Core of Rishirilide B
A route enabling the synthesis of the stereo-triad of rishirilide B (1) from 2-hydroxy-3-methylnaphthalene-1,4-dione, is reported. Key transformations include the regioselective 1,2-Grignard addition to a tautomeric mixture of o- and p-quinones, regioselective carbamoylation of a tautomeric mixture,...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2564814/ https://ncbi.nlm.nih.gov/pubmed/18846264 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-2006-950188 |
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