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Enantiomerically Pure α-Amino Aldehydes from Silylated α-Amino Acids
[Image: see text] The disilylation of α-amino acids 1 to provide 2 (72–87%) was achieved without racemization. An unprecedented borane-mediated semi-reduction strategy was devised to convert 2 to stable, isolable oxazaborolidines 3 (100%) which were hydrolyzed to provide 5 (49–60%) as pure, stable c...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2007
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2563420/ https://ncbi.nlm.nih.gov/pubmed/18092797 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol7028993 |
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