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An Approach to the Total Synthesis of Welwistatin

An approach to the total synthesis of the anti-microtubule agent welwistatin is described. Key transformations include 1) a 7-endo intramolecular conjugate addition reaction of enone 6 to deliver the strained bicyclo[4.3.1]decanone 5; 2) a 6π electrocyclic ring closure of trienecarbamate 1 6 followe...

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Autores principales: Greshock, Thomas J., Funk, Raymond L.
Formato: Artigo
Lenguaje:Inglês
Publicado: 2006
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2547338/
https://ncbi.nlm.nih.gov/pubmed/16737334
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0608799
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