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Nitrosative Cytosine Deamination. An Exploration of the Chemistry Emanating from Deamination with Pyrimidine Ring-Opening
A discussion of nitrosative deamination of cytosine 1 is presented that argues for the formation of 6 by diazotization of 1 to cytosinediazonium ion 2 and its electrostatic complex 3, dediazoniation to 4 ↔ 5, and amide-bond cleavage to 6. The reaction channels available to 6 include hydrolytic degly...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2546522/ https://ncbi.nlm.nih.gov/pubmed/16097794 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx050082a |
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