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Stereochemical control in the reduction of 2-Chromanols
[Image: see text] Reduction of C5-substituted 2-hydroxychromans selectively provides 2,4-cis-chromans using large silane reductants and 2,4-trans-chromans using the smaller silane PhSiH(3). The stereochemical outcome has been rationalized based on a Curtin-Hammett kinetic situation arising from hydr...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2538801/ https://ncbi.nlm.nih.gov/pubmed/17020284 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061727g |
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