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Total Synthesis of Amphidinolide E
A convergent and highly stereocontrolled synthesis of amphidinolide E (1) has been accomplished. The synthesis features a highly diastereoselective (>20:1) BF(3)·Et(2)O promoted [3+2] annulation reaction between aldehyde 3 and allylsilane 4 to afford substituted tetrahydrofuran 2.
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2006
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2538580/ https://ncbi.nlm.nih.gov/pubmed/17165709 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja066663j |
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