Synthesis, Characterization and Study of Octanuclear Iron-Oxo Clusters Containing a Redox-Active Fe(4)O(4)-Cubane Core

A one pot synthetic procedure yields the octanuclear Fe(III)-complexes Fe(8)(μ(4)-O)(4)(μ-pz*)(12)X(4), where X = Cl and pz* = pyrazolate anion (pz = C(3)H(3)N(2)(-)) (1), 4-Cl-pz (2) and 4-Me-pz (3), or X = Br and pz* = pz (4). The crystal structures of complexes 1 – 4, determined by X-ray diffract...

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Hlavní autoři: Baran, Peter, Boča, Roman, Chakraborty, Indranil, Giapintzakis, John, Herchel, Radovan, Huang, Qing, McGrady, John E., Raptis, Raphael G., Sanakis, Yiannis, Simopoulos, Athanasios
Médium: Artigo
Jazyk:Inglês
Vydáno: 2007
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2535771/
https://ncbi.nlm.nih.gov/pubmed/18078337
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic7020337
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