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Metalated Nitriles: Cation-Controlled Cyclizations
Judicious choice of cation allows the selective cyclization of substituted γ-hydroxynitriles to trans- or cis-decalins and trans- or cis-bicyclo[5.4.0]-undecanes. The stereoselectivities are consistent with deprotonations generating two distinctly different metalated nitriles: an internally coordina...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2533635/ https://ncbi.nlm.nih.gov/pubmed/17579448 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol071084k |
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