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Synthesis of an Advanced Intermediate En Route to the Mitomycin Natural Products
An advanced intermediate in our planned synthesis of mitomycin C has been acquired in nine steps from tert-butyl glyoxylate. The aziridinyl pyrrolidine and quinone subunits are coupled regioselectively to arrive at an enamine that is prepared for C10 homologation.
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2533355/ https://ncbi.nlm.nih.gov/pubmed/17165926 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0624676 |
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