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Cofactor-Dependence in Reduction Potentials for [4Fe–4S](2+/1+) in Lysine 2,3-Aminomutase
Lysine 2,3-aminomutase (LAM) catalyzes the interconversion of l-lysine and l-β-lysine by a free radical mechanism. The 5′-deoxyadenosyl radical derived from the reductive cleavage of S-adenosyl-l-methionine (SAM) initiates substrate-radical formation. The [4Fe–4S](1+) cluster in LAM is the one-elect...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2532065/ https://ncbi.nlm.nih.gov/pubmed/16519516 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi0519497 |
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