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Kinetic and Stereochemical Analysis of YwhB, a 4-Oxalocrotonate Tautomerase Homologue in Bacillus subtilis: Mechanistic Implications for the YwhB- and 4-Oxalocrotonate Tautomerase-catalyzed Reactions

YwhB, a 4-oxalocrotonate tautomerase (4-OT) homologue in Bacillus subtilis, has no known biological role and the gene has no apparent genomic context. The kinetic and stereochemical properties of YwhB have been examined using available enol and dienol compounds. The kinetic analysis shows that YwhB...

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Detalhes bibliográficos
Main Authors: Wang, Susan C, Johnson, William H., Czerwinski, Robert M., Stamps, Stacy L., Whitman, Christian P.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2531070/
https://ncbi.nlm.nih.gov/pubmed/17902707
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi701231a
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