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HYDROXIDE-PROMOTED CORE CONVERSIONS OF MOLYBDENUM-IRON-SULFUR EDGE-BRIDGED DOUBLE CUBANES: OXYGEN-LIGATED TOPOLOGICAL P(N) CLUSTERS
The occurence of a heteroatom X (C, N, or O) in the MoFe(7)S(9)X core of the iron-molybdenum cofactor of nitrogenase has encouraged synthetic attempts to prepare high nuclearity M-Fe-S-X clusters containing such atoms. We have previously shown that reaction of the edge-bridged double cubane [(Tp)(2)...
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| Huvudupphovsmän: | , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2007
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2527064/ https://ncbi.nlm.nih.gov/pubmed/17892284 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic701070w |
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