Stabilization of Reduced Molybdenum-Iron-Sulfur Single and Double Cubane Clusters by Cyanide Ligation

Recent work has shown that cyanide ligation increases the redox potentials of Fe(4)S(4) clusters, enabling the isolation of [Fe(4)S(4)(CN)(4)](4−), the first synthetic Fe(4)S(4) cluster obtained in the all-ferrous oxidation state (Scott, T. A.; Berlinguette, C. P.; Holm, R. H.; Zhou, H.-C., Proc. Na...

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Bibliographic Details
Main Authors: Pesavento, Russell P., Berlinguette, Curtis P., Holm, R. H.
Format: Artigo
Language:Inglês
Published: 2007
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2546524/
https://ncbi.nlm.nih.gov/pubmed/17279830
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic061704y
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