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Stereospecific Cross-Coupling of α-(Thiocarbamoyl)organostannanes with Alkenyl, Aryl, and Heteroaryl Iodides

Racemic and scalemic PTC-protected α-hydroxystannanes cross-couple with alkenyl/aryl/heteroaryl iodides in moderate to good yields using copper(I) thiophene-2-carboxylate (CuTC) in THF at or below room temperature. Simple aryl iodides and 1-iodocyclohexene, two classes of electrophiles that typicall...

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Detalhes bibliográficos
Main Authors: Falck, J. R., Patel, Paresh K., Bandyopadhyay, Anish
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2526971/
https://ncbi.nlm.nih.gov/pubmed/17243814
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja064948q
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