Diastereoselective Diels–Alder Reactions of N-Sulfonyl-1-aza-1,3-butadienes With Optically Active Enol Ethers: An Asymmetric Variant of the 1-Azadiene Diels–Alder Reaction

The first detailed study of a room temperature asymmetric Diels–Alder reaction of N-sulfonyl-1-aza-1,3-butadienes enlisting a series of nineteen enol ethers bearing chiral auxilaries is reported with many providing highly diastereoselective (endo and facial diastereoselection) reactions largely the...

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Bibliographic Details
Main Authors: Clark, Ryan C., Pfeiffer, Steven S., Boger, Dale L.
Format: Artigo
Language:Inglês
Published: 2006
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2525448/
https://ncbi.nlm.nih.gov/pubmed/16492042
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0571646
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