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Isotope Effects on the Enzymatic and Non-Enzymatic Reactions of Chorismate
The important biosynthetic intermediate chorismate reacts thermally by two competitive pathways, one leading to 4-hydroxybenzoate via elimination of the enolpyruvyl side chain, and the other to prephenate by a facile Claisen rearrangement. Measurements with isotopically labeled chorismate derivative...
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| Main Authors: | , , , , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2005
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2519010/ https://ncbi.nlm.nih.gov/pubmed/16159290 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja052929v |
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