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Formal Synthesis of (±)-Platensimycin
Reductive alkylation of 5-methoxy-1-tetralone (6) with 2,3-dibromopropene gave an equilibrium mixture of bicyclic diones 7 (51%) and 8 (35%). Radical cyclization of 7 afforded tricyclic dione 5 (84%), which was reduced, cyclized and dehydrated to give tetracyclic alkene 13 in 63% yield. Allylic oxid...
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| Glavni autori: | , , , , |
|---|---|
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2007
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2518405/ https://ncbi.nlm.nih.gov/pubmed/17407302 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol070563g |
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