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Bi(OTf)(3)-Catalyzed 5-Exo-Trig Cyclization via Halide Activation

Lewis acid activation of allyl halides utilizing Bi(OTf)(3) resulted in cationic cyclization of alkenes with high efficiency. While other Lewis acids could catalyzed this process with highly substituted alkenes, bismuth salts demonstrated unique reactivity in come cases. This suggested that bismuth...

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Detalhes bibliográficos
Main Authors: Hayashi, Ryuji, Cook, Gregory R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2516941/
https://ncbi.nlm.nih.gov/pubmed/19122872
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2008.04.067
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