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Total Synthesis of (−)- Senepodine G and (−)-Cermizine C
An efficient, stereospecific synthesis of the alkaloids senepodine G (2) and cermizine C (1) has been completed using the BF(3)·Et(2)O promoted stereospecific addition of Me(2)CuLi toα,β-unsaturated lactam 6 to provide lactam 3, the addition of MeMgBr followed by HCl to convert 3 to senepodine G (2)...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2515611/ https://ncbi.nlm.nih.gov/pubmed/17253832 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo062067w |
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