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Characterization of SpnQ from the Spinosyn Biosynthetic Pathway of Saccharopolyspora spinosa: Mechanistic and Evolutionary Implications for C-3 Deoxygenation in Deoxysugar Biosynthesis
The C-3 deoxygenation step in the biosynthesis of D-forosamine (4-N,N-dimethylamino-2,3,4,6-tetradeoxy-D-threo-hexopyranose), a constituent of spinosyn produced by Saccharopolyspora spinosa, was investigated. The spnQ gene, proposed to encode a TDP-4-keto-2,6-dideoxy-D-glucose 3-dehydratase was clon...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2515268/ https://ncbi.nlm.nih.gov/pubmed/17076492 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja0649670 |
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