Llwytho...

Total Synthesis of TMC-95A and -B via a New Reaction Leading to Z-Enamides. Some Preliminary Findings as to SAR

A full account of the total syntheses of proteasome inhibitors TMC-95A and -B is provided. A key feature of the syntheses involved installation of a cis-propenylamide moiety by a thermal rearrangement of an α-silylallyl amide. The scope and mechanism of the enamide-forming reaction are discussed. Al...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Prif Awduron: Lin, Songnian, Yang, Zhi-Qiang, Kwok, Benjamin H. B., Koldobskiy, Michael, Crews, Craig M., Danishefsky, Samuel J.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: 2004
Pynciau:
Mynediad Ar-lein:https://ncbi.nlm.nih.gov/pmc/articles/PMC2507741/
https://ncbi.nlm.nih.gov/pubmed/15149232
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja049821k
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