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Characterization of the Arene-Oxidizing Intermediate in ToMOH as a Diiron(III) Species

We report the generation and characterization of a diiron(III) intermediate formed during reaction with dioxygen of the reduced hydroxylase component of toluene/o-xylene monooxygenase from Pseudomonas sp. OX1. The decay rate of this species is accelerated upon mixing with phenol, a substrate for thi...

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Bibliografske podrobnosti
Main Authors: Murray, Leslie J., Naik, Sunil G., Ortillo, Danilo O., García-Serres, Ricardo, Lee, Jessica K., Huynh, Boi Hanh, Lippard, Stephen J.
Format: Artigo
Jezik:Inglês
Izdano: 2007
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2494525/
https://ncbi.nlm.nih.gov/pubmed/17967027
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja076121h
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