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Characterization of the Arene-Oxidizing Intermediate in ToMOH as a Diiron(III) Species
We report the generation and characterization of a diiron(III) intermediate formed during reaction with dioxygen of the reduced hydroxylase component of toluene/o-xylene monooxygenase from Pseudomonas sp. OX1. The decay rate of this species is accelerated upon mixing with phenol, a substrate for thi...
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| Autores principales: | , , , , , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2007
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2494525/ https://ncbi.nlm.nih.gov/pubmed/17967027 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja076121h |
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