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Twofold C–H Functionalization: Palladium-catalyzed ortho Arylation of Anilides
The ortho arylation of anilides to form biphenyls via a twofold C–H functionalization/C–C bond-forming process is described. The oxidative coupling takes place in the presence of 5–10 mol % Pd(OAc)(2), 10–20 mol % DMSO, and 4–11 equivalents of the aryl substrate in TFA under an oxygen atmosphere. No...
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| Main Authors: | , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2008
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2489205/ https://ncbi.nlm.nih.gov/pubmed/18465866 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol800619c |
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