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Diastereoselective Synthesis of the Pectenotoxin 2 Non-Anomeric AB Spiroacetal
The reductive cyclization reaction of a cyanoacetal has been used to prepare the pectenotoxin 2 (PTX-2) AB spiroacetal with high diastereoselectively for the first time. The strategy is convergent and makes use of the axial-selective reductive lithiation of 2-cyano tetrahydropyran rings to introduce...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2487677/ https://ncbi.nlm.nih.gov/pubmed/17286378 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol0630447 |
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