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Unified Synthesis of C(19)–C(26) Subunits of Amphidinolides B(1), B(2), and B(3) by Exploiting Unexpected Stereochemical Differences in Crimmins’ and Evans’ Aldol Reactions
The efficient synthesis of the C(19)–C(26) subunit of amphidinolide B(1) and B(2) has been completed using a boron-mediated aldol reaction. The synthesis of the C(19)–C(26) subunit of amphidinolide B(3) has also been accomplished through an unexpected anti aldol reaction using a titanium-mediated pr...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2004
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2430272/ https://ncbi.nlm.nih.gov/pubmed/15049660 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo035829l |
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