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Efficient synthesis of the C(7)–C(20) subunit of amphidinolides C and F

Synthesis of the C(7)–C(20) subunit of amphidinolides C and F has been accomplished utilizing a Me(3)Al-mediated ring opening of a vinyl iodide/allylic epoxide to establish the C(12,13) anti stereochemistry, an organolithium coupling/olefination sequence to construct the C(9)–C(11) diene moiety and...

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Detalhes bibliográficos
Main Authors: Mahapatra, Subham, Carter, Rich G.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2830907/
https://ncbi.nlm.nih.gov/pubmed/19865690
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b916744g
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