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Vinyl Tris(trimethylsilyl)silanes: Substrates for Hiyama Coupling
The oxidative treatment of vinyl tris(trimethylsilyl)silanes with hydrogen peroxide in aqueous sodium hydroxide in tetrahydrofuran generates reactive silanol or siloxane species that undergo Pd-catalyzed cross-couplings with aryl, heterocyclic and alkenyl halides in the presence of Pd(PPh(3))(4) and...
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2008
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2430103/ https://ncbi.nlm.nih.gov/pubmed/19478830 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.03.024 |
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