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Synthesis of (±)-Brazilin Using IBX
A short synthesis of (±)-brazilin is reported. This synthesis uses several interesting and underutilized transformations including a regioselective dirhodium-catalyzed aryl C–H insertion, a regioselective IBX phenol → o-quinone oxidation, a tautomerization of an o-quinone to a p-quinone methide, and...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2005
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2423948/ https://ncbi.nlm.nih.gov/pubmed/16354080 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/o1023749 |
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