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Chemical and Traditional Mutagenesis of Vaccinia DNA Topoisomerase Provides Insights to Cleavage Site Recognition and Transesterification Chemistry

Vaccinia DNA topoisomerase IB (TopIB) relaxes supercoils by forming and resealing a covalent DNA-(3′-phosphotyrosyl)-enzyme intermediate. Here we gained new insights to the TopIB mechanism through “chemical mutagenesis.” Meta-substituted analogs of Tyr(274) were introduced by in vitro translation in...

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Détails bibliographiques
Auteurs principaux: Yakovleva, Lyudmila, Chen, Shengxi, Hecht, Sidney M., Shuman, Stewart
Format: Artigo
Langue:Inglês
Publié: American Society for Biochemistry and Molecular Biology 2008
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC2414267/
https://ncbi.nlm.nih.gov/pubmed/18367446
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M801595200
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