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Bias and error in estimates of equilibrium free-energy differences from nonequilibrium measurements
In 1997, Jarzynski proved a remarkable equality that allows one to compute the equilibrium free-energy difference ΔF between two states from the probability distribution of the nonequilibrium work W done on the system to switch between the states, e(–Δ)(F)(/kT) = 〈e(–)(W)(/kT)〉, [Jarzynski, C. (1997...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2003
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC240657/ https://ncbi.nlm.nih.gov/pubmed/14528008 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1635159100 |
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