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Concise, Biomimetic Total Synthesis of d,l-Marcfortine C

A biomimetic total synthesis of the fungal metabolite marcfortine C utilizing an intramolecular Diels-Alder reaction is described. In addition, a key stereoselective oxaziridine-mediated oxidation/pinacol rearrangement of indole 24 was used to complete the total synthesis.

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Detalhes bibliográficos
Main Authors: Greshock, Thomas J., Grubbs, Alan W., Williams, Robert M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2346435/
https://ncbi.nlm.nih.gov/pubmed/18596842
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2007.03.016
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