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Water inertial reorientation: Hydrogen bond strength and the angular potential

The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy of the hydroxyl stretching mode (OD of dilute HOD in H(2)O). The anisotropy decay displays a sharp drop at very short times caused by inertial orientational motion, followed by a much slower dec...

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Detalhes bibliográficos
Main Authors: Moilanen, David E., Fenn, Emily E., Lin, Yu-Shan, Skinner, J. L., Bagchi, B., Fayer, Michael D.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2008
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2291089/
https://ncbi.nlm.nih.gov/pubmed/18381817
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0801554105
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