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Ion–water hydrogen-bond switching observed with 2D IR vibrational echo chemical exchange spectroscopy

The exchange of water hydroxyl hydrogen bonds between anions and water oxygens is observed directly with ultrafast 2D IR vibrational echo chemical exchange spectroscopy (CES). The OD hydroxyl stretch of dilute HOD in H(2)O in concentrated (5.5 M) aqueous solutions of sodium tetrafluoroborate (NaBF(4...

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Detalhes bibliográficos
Main Authors: Moilanen, David E., Wong, Daryl, Rosenfeld, Daniel E., Fenn, Emily E., Fayer, M. D.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2626710/
https://ncbi.nlm.nih.gov/pubmed/19106293
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0811489106
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