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Catalysis of imido-group hydrolysis in a maleimide conjugate

Maleimides are often used for biomolecular conjugation with thiols. An underappreciated aspect of the imido group in a maleimide conjugate is its susceptibility to spontaneous hydrolysis, resulting in undesirable heterogeneity. Here, a chromophoric maleimide is used to demonstrate that both molybdat...

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Detalhes bibliográficos
Main Authors: Kalia, Jeet, Raines, Ronald T.
Formato: Artigo
Idioma:Inglês
Publicado em: 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2245990/
https://ncbi.nlm.nih.gov/pubmed/17881230
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmcl.2007.09.002
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