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Solvent-controlled regioselective protection of allyl-4,6-benzylidene glucopyranosides

We wish to report a simple synthetic procedure, which permits the regiospecific mono-acylation, alkylation and silylation at the 2-position of allyl 4,6-O-benzylidene α-D-glucopyranoside in high yields and which does not require the use of catalysts.

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Detalhes bibliográficos
Main Authors: Ness, Kerry Ann, Migaud, Marie E
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2048501/
https://ncbi.nlm.nih.gov/pubmed/17897436
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1186/1860-5397-3-26
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