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Enantioselective Transaminations by Dendrimeric Enzyme Mimics
PAMAM dendrimers have been constructed with a pyridoxamine core, and chiral capping amino groups. Transamination to form phenylalanine and alanine from their related ketoacids produced enantioselectivities induced by the formally remote chiral caps, supporting computer models that indicate folding o...
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Main Authors: | , , |
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Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2007
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2031867/ https://ncbi.nlm.nih.gov/pubmed/18596840 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2007.02.052 |
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