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Reactivity-promoting criterion based on internal vibrational energy redistribution
We propose to introduce intrinsic dynamical properties as a criterion for promoting reactivity of small size noble metal reactive centers relevant for heterogeneous catalysis. To illustrate the concept, collisions between Ag(6)(−) or Au(6)(−) clusters and molecular oxygen have been investigated with...
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| Glavni autori: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
National Academy of Sciences
2007
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1965510/ https://ncbi.nlm.nih.gov/pubmed/17566104 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0704066104 |
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