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Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes
Addition of a sterically demanding cyclic (alkyl)(amino)carbene (CAAC) to AuCl(SMe(2)) followed by treatment with [Et(3)Si(Tol)](+)[B(C(6)F(5))(4)](−) in toluene affords the isolable [(CAAC)Au(η(2)-toluene)](+)[B(C(6)F(5))(4)](−) complex. This cationic Au(I) complex efficiently mediates the catalyti...
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| Main Authors: | , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2007
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1959421/ https://ncbi.nlm.nih.gov/pubmed/17698808 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0705809104 |
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