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A Dipolar Cycloaddition Approach Toward the Kopsifoline Alkaloid Framework
Using a metal-catalyzed domino reaction as the key step, the heterocyclic skeleton of the kopsifoline alkaloid family was constructed by a 1,3-dipolar cycloaddition of a carbonyl ylide dipole derived from a Rh(II)-catalyzed reaction of a diazo ketoester across the indole π-bond. Ring opening of the...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1948834/ https://ncbi.nlm.nih.gov/pubmed/17710185 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2007.01.064 |
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