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Local viscosity of supercooled glycerol near T(g) probed by rotational diffusion of ensembles and single dye molecules
We probe the rotational diffusion of a perylene dye in supercooled glycerol, 5–25 K above the glass-transition temperature (T(g) = 190 K) at the ensemble and the single-molecule level. The single-molecule results point to a broad distribution of local viscosities that vary by a factor of five or mor...
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| Autors principals: | , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2007
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC1937517/ https://ncbi.nlm.nih.gov/pubmed/17488815 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0610521104 |
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